News:

Thermal Physics and Thermodynamics

Science caught in the Web 2010-08-21

posted Saturday, 21 August 2010 08:21

  • Stuff
    • The Hubble Constant, Mike Guidry, University of Tennessee–Knoxville
      This just may be the oldest page on the Web — 1994! Like all scientific measurements, this one is stated as a range from 50 to 100 megaparsecs per km/s. (The Hubble constant is stated in unusual units for historical reasons.) Current measurements are all around 71–72 Mpc/km/s. In 1994, the uncertainty in the Hubble constant was of the same order as the quantity itself. Current measurments have an uncertainty of a few per cent. Cosmology has advanced quite a bit in the past 16 years. Also note the quaint little instruction at the bottom of the page. "Use the ‘Back’ button on the browser to return." Lastly, if you look at the source code, you’ll see the page doesn’t come with a Document Type Definition (DTD). That means it goes back to the days when there was only one kind of html. In 1994 the Web was only 4 years old and graphical browsers were only 2 years old. The Web has seen astronomical changes since then.
  • All global climate data basically come from one of three sources.
  • YouTube videos
    • Bob Hoover in his Aero Commander Shrike, BBC. Posted to YouTube by flyboy172r.
      Near the end of the clip, Bob Hoover pours a glass of tea while doing a barrel roll. Not drop is spilled.
    • Thrust SSC – Sonic Boom. Posted to YouTube by rodybolands.
      Thrust is a supersonic car powered by Rolls Royce jet engines and is the current holder of the world land speed record.
    • STS-124 Launch w/ Sound. Posted to YouTube by plunderingthe7cs.
      Raw video taken from one of the space shuttle’s solid rocket boosters. Reminiscent of a scene from Kubrick’s 2001: A Space Odyssey. Thanks to Physics Buzz for the tip.

physics.info/news/?p=2557

Joule

posted Tuesday, 17 August 2010 04:06

Excerpt from the section on Work.

The SI unit of work is the joule.

[ J = Nm = kg m2/s2 ]

Work and energy can be expressed in the same units. Unfortunately, there are a lot of units for energy beside the joule. (This is discussed in another section of this book.) The ones most commonly seen in the US in the early Twenty-first Century are probably calorie (diet and nutrition), Btu (heating and cooling), kilowatt hour (electric bills), therm (natural gas bills), quad (macroeconomics), ton of TNT (nuclear weapons), erg (older scientists), and foot pound (older engineers). The first two in this list, the calorie and the Btu, were first introduced by Nineteenth Century scientists studying calorimetry. (The French gave us the calorie and the English gave us the British thermal unit or Btu.) The last one in the list, the foot pound, was introduced by Nineteenth Century scientists studying mechanics. In the Nineteenth Century, calorimetry and mechanics were separate disciplines. Calorimetry is the study of heat. Mechanics is the study of motion and forces. A learned gentleman (and they usually were men at this time) might study both, but he probably didn’t link them in any significant way. That is, unless his name was Joule.

James Prescott Joule (1818–1889) was a wealthy English brewer who dabbled in various aspects of science and economics. Sometimes these endeavors overlapped. He invented the foot pound as a unit of work. (Foot being the unit of displacement and pound being the unit of force.) This enabled him to quantitatively compare the "economical duty" of different mechanical systems. Coal-fired steam engines were the primary source of industrial might at the time, but electricity was emerging on the high tech horizon. Joule realized that mechanical work, heat, and electric energy were all somehow interconvertible. Heat can do work. Work can make heat. Work can make electricity, Electricity can do work, Electricity can make heat. Heat can make electricity. Energy was something that could take on multiple forms.

Joule’s most famous experiment is probably the determination of the mechanical equivalent of heat (to be discussed in more detail elsewhere in this book, I hope). Heat was measured in British thermal units (by the British at least) and work was measured in foot pounds (which Joule invented). Joule established that one British thermal unit of heat was equivalent to approximately 770 foot pounds of mechanical work. (Very close to today’s value of 778 ft lb/Btu.) This result was essential in the realization that, despite appearing in multiple forms, energy was one thing.

The International System of Units which began to dominate the scientific world in the mid-Twentieth Century was French in origin. Foot pounds and British thermal units had no place in this much more logical and consistent system. 12 inches in a foot. 16 ounces in a pound. 128 ounces in a gallon in the US and who knows how many in the UK. The math was much too difficult. Parlez-vous les unités métriques? The SI was French in origin, but international in nature. When the call went out to name the unit of energy, the answer was Joule! Absolument!

physics.info/news/?p=2538

Predicting Future Climate

posted Tuesday, 30 March 2010 11:50

Snow rarely gets a chance to melt in Antarctica, even in the summer when the sun never sets. In the interior of the continent, the temperature of the air hasn’t been above the freezing point of water in any significant way for the last 900,000 years. The snow that falls there accumulates and accumulates and accumulates until it compresses into rock solid ice — up to 4.5 km thick in some regions. Since the snow that falls is originally fluffy with air, the ice that eventually forms still holds remnants of this air — very, very old air. By examining the isotopic composition of the gases in carefully extracted cores of this ice we can learn things about the past climatic conditions on earth. By extension we might also predict some things about the climate of the future.

The National Climatic Data Center (NCDC) has made available ice core data collected by Petit, et al. at the Vostok Research Station in Antarctica in 1999. An adapted version that unites two different data sets can be found on this website in the file vostok.txt. The columns in this data set are as follows:

  1. Age of air (years before present)
  2. Temperature anomaly with respect to the mean recent value (℃)
  3. Carbon dioxide concentration (ppm)
  4. Dust concentration (ppm)

We begin by plotting the overlapping time series graphs for temperature anomaly and carbon dioxide concentration. The data show a definite correlation. The two quantities go up and down in near synchrony.


[magnify]

Here’s the scatter plot of the two time-varying quantities plotted against one another. The data forms a dense cloud that is roughly oval shaped. The best fit line slices nicely through the data.


[magnify]

Temperature varies linearly with atmospheric carbon dioxide concentration. Low CO2 levels go with a cooler climate and high CO2 levels go with a warmer climate. What does our linear regression analysis predict given current carbon dioxide levels of 386 ppm?

y =  mx + b
y =  (0.0908 ℃/ppm)(386 ppm) − 25.23 ℃
y =  +9.8 ℃

The consensus among working climate scientists is that the globe will warm +5 ℃ on average over the course of the Twenty-first Century. The increase is expected to be smaller than average near the equator and greater than average near the poles. Since the Vostok ice cores were collected in Antarctica, our prediction of approximately +10 ℃ is right in line with those made by more sophisticated means.

Correlation is not causation, however. Graphs like those used in this problem cannot tell us whether carbon dioxide affects temperature, temperature affects carbon dioxide, or some third factor is affecting both. We need a theoretical model that describes which way the cause and effect work. That model will someday be described in more detail in the section of this book that deals with heat transfer by radiation. (Right now it’s just a loose collection of thoughts.)

Carbon dioxide is a greenhouse gas. Its role in atmospheric thermodynamics is much like the glass in a greenhouse. It is transparent to visible light, but not to infrared. Visible light easily punches through the atmosphere. It is absorbed by the ground and then reradiated as infrared. The infrared is partly blocked by the atmosphere and has a hard time escaping out into space. This little delay keeps the earth comfortably warm. Water vapor, carbon dioxide, methane, and other gases have been shown to play a significant role in this process. They all interact with infrared radiation. These properties have been measured in tabletop laboratory experiments that had no direct connection to climatology.

Atmospheric carbon dioxide levels have increased steadily over the past 100 to 150 years. This is due to the burning of coal, petroleum, and natural gas as well as deforestation and other changes in land use associated with the Industrial Revolution. During this same time period, average global temperatures have been generally increasing and there is no reason to believe that this trend will quit anytime soon. Climate models all show that as long as CO2 concentrations stay somewhere around their turn of the Twenty-first Century levels, global temperatures will continue to increase for the next 100 years. This conclusion is based on solid scientific reasoning and is regarded by nearly all climate scientists as valid. The scientific questions that remain unanswered are: how can we increase the precision and reliability of our global climate predictions and what effect will the inevitable changes have on life as we know it? The question of what is to be done about all of this is left to the people to answer.

Let’s move our attention from carbon dioxide to dust. Here are the overlapping time series graphs for temperature anomaly and dust concentration. The correlation with temperature is not as evident for dust as it was for CO2 since the changes are in the opposite direction. High levels of dust seem to correlate with low temperatures.


[magnify]

The relation between dust and temperature becomes more evident when graphed as a scatter plot. It appears that temperature decreases with increasing amounts of dust, but this decrease levels off after awhile. The relationship appears to have a horizontal asymptote like an exponential approach function.


[magnify]

Atmospheric dust correlates to a negative temperature anomaly that exponentially approaches a minimum value. As dust concentration increases, the exponential term of our curve fitting function approaches zero leaving the constant term to stand by itself. This is the limit or asymptote of our curve fit.

  y =  aebx − c  
  ymin =  − c = −7.6 ℃  

So what is going on here? Does dust cause temperatures to drop or do low temperatures make the dust fly? The answer to this question is not so simple. Here we have a real problem of determining causation.

Water vapor, carbon dioxide, methane, and the other greenhouse gases absorb and reradiate infrared radiation because the natural vibrational frequencies of these molecules lie in the infrared part of the electromagnetic spectrum. They don’t vibrate at visible light frequencies, which is why they are all transparent to the light that we see with our eyes.

Dust particles are large compared to molecules. They are also larger than a wavelength of infrared or visible light. Because of this, they are essentially obstacles to infrared and visible light waves. When the sky is full of dust, light has a hard time making it down to the ground. The dust particles scatter a great deal of solar energy back into space and the earth is a little bit cooler as a result. Large volcanoes can spread so much dust into the atmosphere that they sometimes have a measurable effect on climate. The 1991 eruption of Mount Pinatubo in the Philippines caused a globally averaged temperature anomaly of −0.3 ℃ that lasted two years.

Well actually, that last statement isn’t quite right. Mount Pinatubo did spread a lot of ash around the globe (resulting in fantastic sunsets), but the primary mechanism by which it cooled the earth was through the injection of sulfur dioxide into the stratosphere. When SO2 gets together with H2O the result is an aerosol of H2SO4 — sulfuric acid. Aerosols have a greater cooling effect on climate than dust. (They are also notoriously hard to describe in climate models.)

Now let’s examine the reverse causation. A cool climate is a dry one. When temperatures are low, water has a hard time evaporating. Less water vapor means less rain. Less rain means more dust. Maybe dust levels are high when the climate is cool is because a cool climate leads to more dust.

If dust causes cooling, then the coldest dust could ever make the earth would be around −8 ℃ lower than it is now. If cooling causes dust, then all we can say is that there has never been a temperature anomaly lower than −8 ℃ in the last 400,000 years and every time the earth has gotten this cold it’s been very dusty.

This is a practice problem that appears in this book in the sections dealing with radiation, linear regression, and curve fitting.

physics.info/news/?p=1340

Science caught in the Web 2010-02-20

posted Saturday, 20 February 2010 23:00

physics.info/news/?p=1075

Science caught in the Web 2010-01-23

posted Saturday, 23 January 2010 23:59

physics.info/news/?p=965